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VEIN CHARACTERISTICS,
CHEMICAL EVOLUTION AND
MINERAL DEPOSITION IN A LOW SULPHIDATION EPITHERMAL
GOLD-SILVER DEPOSIT AT PAJINGO, NORTHEAST
QUEENSLAND, AUSTRALIA
Renato E. Bobis and Subhash Jaireth
Gold Research Group Geology Department James Cook University
of
North Queensland, Townsville, Queensland, Australia
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ABSTRACT |
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The Palaeozoic Scott Lode gold-silver
deposit, situated at Pajingo, northeast
Queensland, is one of the oldest
reported low sulphidation epithermal
veins. It contains resource of 12 tons
of gold and 47 tons of silver. The
epithermal veins at the Scott Lode are
hosted by feldspathic/volcanolithic
sandstones, quartzose sandstones,
ignimbrites, andesitic volcanic with
interbedded block-and ash-deposits,
lapelli tuffs and andesitic to dioritic
intrusives.
The principal ore and sulphide minerals
include pyrite, sphalerite, galena,
chalcopyrite, hessite, tennantite-
tetrahedrite, argentite, petzite,
electrum and native gold. Vein gangue
minerals consist of quartz, illite,
adularia, and calcite. The main stage
quartz is zoned with respect to
mineralogy, mineralization styles, metal
distribution patterns and vein textures.
Three vertical mineralizatlon zones can
be recognized: l) upper precious metal
zone (PMZ): quartz-pyrite-
electrum-gold- argentite/chalcopyrite,
ii) intermediate precious + base metal
zone (PBMZ): quartz-pyrite-sphalerite
galena-chalcopyrite- hessite-tennantite
tetrahedrite-electrum, and iii) sparse
base metal zone (SBMZ): quartz
-pyrite-sphalerite-galena-chalcopyrite.
The ore interval occurs in the PMZ and
PBMZ with the transition to SBMZ
effectively defining the limit of
mineralizatlon.
Fluid inclusion studies indicate that
precious and base metal mineralization
at the Scott Lode occurred as the
hydrothermal fluidsds cooled. The
homogenization temperatures decrease
with increasing elevation. Cooling of
the hydrothermal fluids via boiling is
considered to be the principal mechanism
in precipitating the vein gangue and ore
minerals. Indicators of hydrothermal
boiling Include the presence of
coexisting liquid- and gas-rich fluid
inclusions in mineralized quartz,
extensive vein brecciation, vein
adularia, bladed calcite and pronounced
crustiform-culloform banding In quartz
veins.
The effects of adiabatic boiling on a
homogeneous aqueous phase employing the
determined and adopted composition of
the hydrothermal fluids responsible for
the Scott Lode deposit have been shown
through an adiabatic modeling study. The
fluid composition used also approximates
that of the ore-bearing hydrothermal
fluids responsible for other low
sulphidation epithermal deposits. In low
sulphidation epithermal conditions, gold
is primarily transported as Au(HS)2,
silver as AgCl2, lead as PbCI3
and PbCl and zinc as ZnCl and Zn(HS)2.
As the fluids undergo adiabatic boiling,
the concentration of H2S
continuously drops and the fluid pH
become slightly more alkaline. These
factors, principally the loss of H2S
would cause the precipitation of
precious and base metals from sulphide
and chloride complexes. Adiabatic
boiling of a fluid with initial
concentration of 2-5 ppb gold at 300°C
can deposit ores containing an average
of 10 ppm Au and 260 ppm Ag. The
precipitation of precious and base
metals is accompanied by the deposition
of adularia, carbonates, quartz and
pyrite. The Au/Ag ratio of the ores
increases with continuous boiling which
may represent the trend commonly
observed in many epithermal deposits.
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